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Chevalier vs. cavalier

The French words chevalier and cavalier both relate to horsemen, but they have distinct meanings and uses in modern French.

Chevalier

B1
Chevalier refers to a knight or a member of certain orders of knighthood. It often carries a noble or honorable connotation.
Le chevalier en armure brillante défendait le château.
(The knight in shining armor defended the castle.)
Il a été fait Chevalier de la Légion d'honneur.
(He was made a Knight of the Legion of Honor.)

Cavalier

A2
Cavalier generally means a horseman or rider. It can also refer to a cavalryman in military contexts.
Le cavalier monte son cheval avec grâce.
(The rider mounts his horse gracefully.)
Les cavaliers de l'armée ont paradé dans la rue principale.
(The army's cavalrymen paraded down the main street.)

Summary

While chevalier typically refers to a knight or an honorable title, cavalier is a more general term for a horseman or rider. Chevalier has historical and noble connotations, while cavalier is used in both military and civilian contexts for anyone who rides a horse.